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Cycloadditions with Silver Ion‐Stabilized (2 RS ,3 RS )‐3‐Methoxy‐ trans ‐Cycloheptene
Author(s) -
Jendralla Heiner
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198010321
Subject(s) - cycloheptene , methanol , deamination , derivative (finance) , chemistry , medicinal chemistry , ion , stereochemistry , organic chemistry , financial economics , economics , enzyme
Stable trans ‐cycloheptene derivative (2a) and (2b) are formed by deamination of (1) in methanol in the presence of AgClO 4 and AgO 3 SCF 3 . The expected cycloadducts, e.g. (3) , are formed by reaction of (2a) with dienes, e.g. 1,3‐cyclohexadiene.