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Novel Photocycloadditions of Dibromomaleimides to 1,3‐Dimethyl‐6‐azauracil
Author(s) -
Szilágyi Géza,
Wamhoff Heinrich
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198010261
Subject(s) - alkylation , pyrimidine , chemistry , molecule , medicinal chemistry , organic chemistry , stereochemistry , catalysis
Possible model reactions for photochemotherapy are the photoreactions of pyrimidine bases and their aza analogues with cyclophilic molecules. The title reaction leads in high yields to (1) , R = H, CH 3 (depending upon the educt). No alkylation products are formed.