Polymetallic Complexes: Complexation of the Triangular Faces of Clusters by the Tripod Ligand, HC(PPh 2 ) 3 | Zendy

Arduini Anita A. | Zendy; Bahsoun Ali A. | Zendy; Osborn John A. | Zendy; Voelker Christian | Zendy

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Polymetallic Complexes: Complexation of the Triangular Faces of Clusters by the Tripod Ligand, HC(PPh 2 ) 3

Author(s) -

Arduini Anita A.,

Bahsoun Ali A.,

Osborn John A.,

Voelker Christian

Publication year - 1980

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198010241

Subject(s) - tripod (photography) , chemistry , ligand (biochemistry) , cluster (spacecraft) , yield (engineering) , crystallography , stereochemistry , physics , receptor , computer science , thermodynamics , optics , programming language , biochemistry

Stabilization of the M 4 cluster in M 4 (CO) 12 carbonyl complexes by the “tripod” ligand HC(PPh 2 ) 3 is accomplished in almost quantitative yield with elimination of 3 CO. In the case of Co 2 Rh 2 (CO) 12 , the ligand adds only to the CoRh 2 faces (and not to the Co 2 Rh faces).

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