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Cobalt Mediated [2 + 2 + 2]‐Cycloadditions: A Simple Route to Substituted Cyclopentadienones
Author(s) -
Gesing Ernst R. F.,
Tane Jeffrey P.,
Vollhardt K. Peter C.
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198010231
Subject(s) - simple (philosophy) , cobalt , chemistry , combinatorial chemistry , organic chemistry , philosophy , epistemology
The production and oxidative demetalation of disilylcyclopentadienonecobalt complexes (1) , n = 2–4, have now been accomplished in preparatively useful yields. These findings are of interest in connection with the synthesis of cyclopentanoid natural products.