Premium
Electrophilic Amination of Cyclopentadienyllithium Compounds
Author(s) -
Bernheim Michael,
Boche Gernot
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198010101
Subject(s) - electrophilic amination , hydroxylamine , amination , chemistry , derivative (finance) , electrophile , salt (chemistry) , organic chemistry , medicinal chemistry , combinatorial chemistry , catalysis , business , finance
A general entry to cyclopentadienylamines (3) is provided by the reaction of (1) with the hydroxylamine derivative (2) . On reaction with n BuLi, (3b) forms the isolable salt Li[C 5 H 4 NMe 2 ], which gives a diaminoferrocene with FeCl 2 .
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom