Selenium‐Catalyzed Reduction of Aromatic Nitro Compounds to Amines by CO/H 2 O in the Presence of Triethylamine | Zendy

Miyata Toshiyuki | Zendy; Kondo Kiyoshi | Zendy; Murai Shinji | Zendy; Hirashima Tsuneaki | Zendy; Sonoda Noboru | Zendy

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Selenium‐Catalyzed Reduction of Aromatic Nitro Compounds to Amines by CO/H 2 O in the Presence of Triethylamine

Author(s) -

Miyata Toshiyuki,

Kondo Kiyoshi,

Murai Shinji,

Hirashima Tsuneaki,

Sonoda Noboru

Publication year - 1980

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198010081

Subject(s) - nitrobenzene , triethylamine , selenium , aniline , nitro , catalysis , chemistry , nitro compound , medicinal chemistry , inorganic chemistry , nuclear chemistry , organic chemistry , alkyl

Reductions with components of water gas (CO/H 2 O) can be catalyzed by selenium; thus nitroarenes are transformed in the presence of metallic selenium and triethylamine into arylamines. H 2 Se may plausibly be assumed as the reaction species. In a control experiment, nitrobenzene and H 2 Se underwent quantitative conversion (under N 2 ) into aniline.

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