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New Arene(dicarbonyl)chromium Chelates: Application to Asymmetric Synthesis of Amines
Author(s) -
SolladiéCavallo Arlette,
Suffert Jean,
Haesslein JeanLuc
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198010051
Subject(s) - chromium , chelation , chemistry , combinatorial chemistry , organic chemistry
A new entry to chiral amines is presented for reaction of (1 S )‐ (1) with CH 3 Li. The amine (−)‐ (2) is formed in 98% chemical and 94% optical yield.