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Transition‐Metal Complexes with Pyrazolyl Bridging Ligands between Very Different Metal Centers
Author(s) -
Stobart Stephen R.,
Dixon Keith R.,
Eadie Donald T.,
Atwood Jerry L.,
Zaworotko Michael D.
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198009312
Subject(s) - bridging (networking) , metal , transition metal , ring (chemistry) , chemistry , connection (principal bundle) , stereochemistry , crystallography , geometry , organic chemistry , computer science , mathematics , catalysis , computer network
The ability of pyrazolyl bridges to form widely differing conformations is of interest in connection with cooperative effects between neighboring metal centers. In (1) , R = Et, the first complex with two pyrazolyl bridges between different metal atoms, the central ring is boat‐shaped.