Transition‐Metal Complexes with Pyrazolyl Bridging Ligands between Very Different Metal Centers | Zendy

Stobart Stephen R. | Zendy; Dixon Keith R. | Zendy; Eadie Donald T. | Zendy; Atwood Jerry L. | Zendy; Zaworotko Michael D. | Zendy

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Transition‐Metal Complexes with Pyrazolyl Bridging Ligands between Very Different Metal Centers

Author(s) -

Stobart Stephen R.,

Dixon Keith R.,

Eadie Donald T.,

Atwood Jerry L.,

Zaworotko Michael D.

Publication year - 1980

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198009312

Subject(s) - bridging (networking) , metal , transition metal , ring (chemistry) , chemistry , connection (principal bundle) , stereochemistry , crystallography , geometry , organic chemistry , computer science , mathematics , catalysis , computer network

The ability of pyrazolyl bridges to form widely differing conformations is of interest in connection with cooperative effects between neighboring metal centers. In (1) , R = Et, the first complex with two pyrazolyl bridges between different metal atoms, the central ring is boat‐shaped.

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