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Upright Unsymmetrical Coordination in a Cyclopropenylnickel Complex: Synthesis and Structure of [(C 3 Ph 3 )Ni(PPh 3 ) 2 ]PF 6
Author(s) -
Mealli Carlo,
Midollini Stefano,
Moneti Simonetta,
Sacconi Luigi
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198009311
Subject(s) - platinum , nickel , coordination complex , crystallography , chemistry , stereochemistry , metal , organic chemistry , catalysis
The novel “upright” coordination of the cyclopropenylium ion has been observed in the nickel complex (1) , the title compound. In the formally analogous platinum complex (2) , C 3 Ph 3 is likewise unsymmetrically coordinated, but “in plane”.