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Spiropentene
Author(s) -
Bloch Robert,
Denis JeanMarc
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198009282
Subject(s) - hydroquinone , trace (psycholinguistics) , furan , chemistry , medicinal chemistry , philosophy , organic chemistry , linguistics
The first spiropentene (1) synthesized , with can be stored for several days at −30°C in CHCl 3 / t BuOH (+ a trace of hydroquinone), is much more reactive than 3,3‐disubstituted cyclopropenes. For example, it adds cyclo‐pentadiene and furan already at 0°C.