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1,3,2‐Dithiaplumbocanes—Heterocycles with Lead( IV )—Sulfur Bonds
Author(s) -
Dräger Martin,
Kleiner Norbert
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198009231
Subject(s) - sulfur , trigonal crystal system , lead (geology) , chemistry , stereochemistry , crystallography , crystal structure , organic chemistry , geology , geomorphology
For investigations on the coordination of lead( IV ) to sulfur , which should contribute to an understanding of the biocycle of‐lead, (1) and (2) , and the latter's S‐analogue were used as model systems. In (1) pb is trigonal‐bipy‐ramidally coordinated, in (2) it is penta‐ or hexacoordinated, depending on the crystal form.