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Proton and Hydrogen Affinity of Furan and the Site of Protonation in the Gas Phase
Author(s) -
Houriet Raymond,
Schwarz Helmut,
Zummack Waltraud
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198009051
Subject(s) - protonation , furan , ion cyclotron resonance , chemistry , electrophile , proton , proton affinity , hydrogen , phase (matter) , gas phase , enol , photochemistry , ion , cyclotron , organic chemistry , physics , catalysis , nuclear physics
Ion cyclotron resonance measurements on D‐labeled furan revealed that in the prototype electrophilic reactions— i.e. protonation—furan behaves in the gas phase as a typical arene and not as enol ether.