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(Trifluoromethyl)fluorogermanates
Author(s) -
Brauer David J.,
Bürger Hans,
Eujen Reint
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198008361
Subject(s) - trifluoromethyl , trigonal bipyramidal molecular geometry , octahedron , chemistry , aqueous solution , fluorine , ligand (biochemistry) , crystallography , trigonal crystal system , stereochemistry , inorganic chemistry , organic chemistry , crystal structure , receptor , biochemistry , alkyl
Germanates containing fluorine and trifluoromethyl ligands are generally accessible by the pathways shown below. In aqueous solution X ⊖ (X = Cl, Br, I) in the starting compound can be quantitatively precipitated by Ag ⊕ . As expected, the ligand geometry is octahedral in the dianions, and trigonal‐bipyramidal in the monoanions.