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A Cationic Ethylene(hydrio)iridium( III ) Complex
Author(s) -
Olgemöller Bernhard,
Beck Wolfgang
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198008341
Subject(s) - iridium , hydroformylation , cationic polymerization , ethylene , catalysis , chemistry , nuclear magnetic resonance spectroscopy , rhodium , medicinal chemistry , photochemistry , polymer chemistry , organic chemistry
The simplest model so far available for an intermediate of catalytic hydrogenation and hydroformylation of olefins is the title compound (1) which could be isolated and characterized by 1 H‐NMR spectroscopy and by reaction with Re(CO) 5 ⊖ .