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Fluoride‐Induced Fragmentation of Trimethylsilyloxysulfonates to Form cis ‐Coupled Hexahydrozulenones
Author(s) -
Tietze LutzF.,
Reichert Ulrich
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198008301
Subject(s) - fragmentation (computing) , fluoride , chemistry , combinatorial chemistry , computer science , inorganic chemistry , operating system
The cis ‐hydroazulenone system (2) valuable for the synthesis of natural products has become more readily accessible through the title reaction. This novel fragmentation can also be performed in the presence of many functional groups.