Formation of Pyrrolnitrin and 3‐(2‐Amino‐3‐chlorophenyl)pyrrole from 7‐Chlorotryptophan | Zendy

van Pée KarlHeinz | Zendy; Salcher Olga | Zendy; Lingens Franz | Zendy

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Formation of Pyrrolnitrin and 3‐(2‐Amino‐3‐chlorophenyl)pyrrole from 7‐Chlorotryptophan

Author(s) -

van Pée KarlHeinz,

Salcher Olga,

Lingens Franz

Publication year - 1980

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198008281

Subject(s) - metabolite , pyrrole , biosynthesis , chemistry , antifungal , connection (principal bundle) , metabolism , secondary metabolite , biochemistry , antibiotics , stereochemistry , biology , microbiology and biotechnology , organic chemistry , enzyme , gene , mathematics , geometry

Little is known about chlorinations in secondary metabolism. In connection with the biosynthesis of the antifungal antibiotic pyrrolnitrin (2) , NO 2 in place of NH 2 , the metabolite (2) has now been isolated for the first time. The intermediates (1) and (3) were elucidated on a previous occasion.

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