Catalytic Synthesis of Magnesium Hydride under Mild Conditions | Zendy

Bogdanović Borislav | Zendy; Liao Shihtsien | Zendy; Schwickardi Manfred | Zendy; Sikorsky Peter | Zendy; Spliethoff Bernd | Zendy

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Catalytic Synthesis of Magnesium Hydride under Mild Conditions

Author(s) -

Bogdanović Borislav,

Liao Shihtsien,

Schwickardi Manfred,

Sikorsky Peter,

Spliethoff Bernd

Publication year - 1980

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198008181

Subject(s) - magnesium , catalysis , magnesium hydride , hydride , halide , hydrogen storage , chemistry , inorganic chemistry , titanium , hydrogen , chromium , organic chemistry

Magnesium hydride, of potential use for reversible storage of hydrogen , has now been synthesized by a method proceeding under mild conditions and which can be performed on a large scale. Especially active catalysts are obtained by reaction of anthracenemagnesium with halides of chromium, titanium, or iron in THF. These solutions are catalytically active at 20°C and under normal pressure.

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