Diagonal Interaction in the Four‐Membered Ring. Experimental Demonstration of a Dominating Circumannular Conjugation: 5,6‐Dimethylenebicyclo[2.1.1]hexane | Zendy

Martin HansDieter | Zendy; EckertMaksić Mirjana | Zendy; Mayer Bernhard | Zendy

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Diagonal Interaction in the Four‐Membered Ring. Experimental Demonstration of a Dominating Circumannular Conjugation: 5,6‐Dimethylenebicyclo[2.1.1]hexane

Author(s) -

Martin HansDieter,

EckertMaksić Mirjana,

Mayer Bernhard

Publication year - 1980

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198008071

Subject(s) - diagonal , ring (chemistry) , planar , hexane , space (punctuation) , chemistry , stereochemistry , mathematics , crystallography , geometry , organic chemistry , computer science , computer graphics (images) , operating system

Which interaction predominates in planar 1,3‐dimethylenecyclobutane (1): circumannular through‐bond conjugation or transannular through‐space conjugation? PE spectroscopic comparison with compounds (2)‐(4) suggests the former alternative.

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