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Lithium Dibenzoylphosphide · 1,2‐Dimethoxyethane—A New 2‐Phospha‐1,3‐dionate
Author(s) -
Becker Gerd,
Birkhahn Matthias,
Massa Werner,
Uhl Werner
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198007411
Subject(s) - dimethoxyethane , lithium (medication) , ring (chemistry) , dimer , chemistry , crystal structure , medicinal chemistry , stereochemistry , crystallography , organic chemistry , psychology , electrode , electrolyte , psychiatry
The lithium compound (1) was formed in place of dibenzoylphosphane on reaction of LiPH 2 DME with PhCOCI. In its crystal, (1) exists as a dimer having a four‐membered (LiOLiO) ring and pentacoordinated lithium.