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N ‐Sulfinylnonafluorobutanesulfonamide—A Supernucleophile
Author(s) -
Bussas Reinhard,
Kresze Günter
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198007321
Subject(s) - transformation (genetics) , image (mathematics) , mathematics , pure mathematics , computer science , chemistry , artificial intelligence , biochemistry , gene
The transformation of a highly reactive enophile into the supernucleophile (1) has been accomplished by formal replacement of p ‐tolyl by n ‐C 4 F 9 . The readily accessible compound (1) is some 10 3 to 10 4 times as active as its p ‐tolyl analogue.
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