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Facile Synthesis of α‐ and β‐ O ‐Glycosyl Imidates; Preparation of Glycosides and Disaccharides
Author(s) -
Schmidt Richard R.,
Michel Josef
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198007311
Subject(s) - glycosyl , glycoside , chemistry , glycosyl donor , stereochemistry , organic chemistry , combinatorial chemistry
Simplification of glycoside and saccharide syntheses is possible with the aid of the readily isolable β‐ and α‐glycosyl imidates (1) and (2) . These key compounds are conveniently prepared from C‐1‐unprotected glucopyranose. Compounds of type (2) were formerly unknown.