Asymmetric Synthesis of Amines by Carbon‐Carbon Coupling in the α‐Position to Nitrogen | Zendy

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Asymmetric Synthesis of Amines by Carbon‐Carbon Coupling in the α‐Position to Nitrogen

Author(s) -

Kolb Michael,

Barth Jacqueline

Publication year - 1980

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198007251

Subject(s) - nitrogen , carbon fibers , optically active , asymmetric carbon , position (finance) , coupling (piping) , chemistry , reinforced carbon–carbon , amino acid , organic chemistry , combinatorial chemistry , stereochemistry , materials science , biochemistry , finance , composite number , economics , composite material , metallurgy

Optically active amines of type (3) and (4) from propargylamine (1) can be obtained by use of the chiral auxiliary compound (S)‐(2) ; the auxiliary compound is recycled in this synthesis. (3) and (4) can be transformed, for example, into amino acids and heterocycles.

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