Synthesis of the First Methylidyne‐Rhodium Cluster by Proton‐Induced H 2 /CH 4 ‐Elimination from a μ‐Methylene Complex | Zendy

Herrmann Wolfgang A. | Zendy; Plank Johann | Zendy; Guggolz Ernst | Zendy; Ziegler Manfred L. | Zendy

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Synthesis of the First Methylidyne‐Rhodium Cluster by Proton‐Induced H 2 /CH 4 ‐Elimination from a μ‐Methylene Complex

Author(s) -

Herrmann Wolfgang A.,

Plank Johann,

Guggolz Ernst,

Ziegler Manfred L.

Publication year - 1980

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198006511

Subject(s) - methylene , rhodium , protonation , cluster (spacecraft) , chemistry , proton , carbyne , crystallography , stereochemistry , medicinal chemistry , physics , catalysis , organic chemistry , nuclear physics , computer science , operating system , ion , carbene

The transformation of a μ‐methylene‐dirhodium complex into a μ 3 ‐methylidyne‐trirhodium complex (X‐ray structure analysis) has been accomplished in reaction (1) → (3) . The first step is protonation of (1) to form the (isolable) μ‐hydrido complex (2) .

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