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Cyclotri(phosphazene) Complexes with P ‐Coordinated PdX 2 and PtX 2
Author(s) -
Schmidpeter Alfred,
Blanck Klaus,
Hess Heinz,
Riffel Heinz
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198006501
Subject(s) - phosphazene , metal , chemistry , crystallography , polymer chemistry , polymer , organic chemistry
The first cyclotriphosphazenes with P ‐coordinated metal (2) are formed on treatment of (1) with PdCl 2 or K 2 PtCl 4 via a 1,2‐H shift. X‐ray structure analysis was performed in the case of (2) , M = Pd, X = Cl. In the other metalated cyclotriphosphazenes the metal (Li, Cu 1 ) is N ‐coordinated.