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Phatolysis of Water Catalyzed by Transition Metal Dithiolenes
Author(s) -
Henning Rainer,
Schlamann Wilhelm,
Kisch Horst
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198006452
Subject(s) - catalysis , transition metal , cleavage (geology) , chemistry , photochemistry , irradiation , metal , materials science , organic chemistry , physics , fracture (geology) , nuclear physics , composite material
As potential catalysts for the photochemical cleavage of water , attention has been focused on compounds of type (1) , especially (1a) , n = 2, M = Ni, R = Ph, z = 0. Irradiation (λ ≥ 290 nm) of (1) in neutral THF/H 2 O solution does indeed produce H 2 , part of it coming from the THF.