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Molecular and Crystal Structure of β‐SeBr
Author(s) -
Katryniok Detlef,
Kniep Rüdiger
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198006451
Subject(s) - dihedral angle , molecule , crystal structure , van der waals force , crystal (programming language) , chemistry , crystallography , organic chemistry , hydrogen bond , computer science , programming language
A contribution to the structural chemistry of compounds of type A 2 B 2 (A = S, Se; B = F, Cl, Br) is provided by the X‐ray structure analysis of β‐SeBr at −80°C. The BrSeSeBr molecules (SeSe = 2.241 Å; dihedral angle 93.58°) are arranged in the crystal in such a manner that some of the Se…Br contacts are significantly closer than the sum of the van der Waals radii.
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