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N ‐Fluoroiminosulfur Tetrafluoride, FNSF 4
Author(s) -
DesMarteau Darryl D.,
Seppelt Konrad
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198006431
Subject(s) - tetrafluoride , physics , molecule , chemistry , organic chemistry
The simplest fluorinated sulfur( VI ) imide has been synthesized starting from Cl 2 NSF 5 . The molecule of (1) is rigid with theNF group in an equatorial position. For comparison: CH 3 NSF 4 and OSF 4 are mobile, whereas CH 2 SF 4 is likewise rigid.
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