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Permethylated Electron‐Excess Metallocenes
Author(s) -
Koelle Ulrich,
Khouzami Fouad
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198006401
Subject(s) - electrophile , nickelocene , electron , chemistry , medicinal chemistry , inorganic chemistry , photochemistry , organic chemistry , physics , nuclear physics , catalysis , ferrocene , electrode , electrochemistry
The new compounds permethylcobaltocene and ‐nickelocene show some surprising reactions which are impossible in the case of the parent compounds. For example, as the first neutral 20‐electron complex, permethyl‐nick‐elocene adds electrophiles R′X to form the novel salts (1) , which are stable to air and water.