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Transition‐Metal Complexes of Malonaldehyde and Dithiomalonaldehyde
Author(s) -
MuellerWesterhoff Ulrich T.,
Alscher Arnold
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198006381
Subject(s) - steric effects , electron delocalization , delocalized electron , transition metal , chemistry , crystallography , planar , spectral line , metal , nmr spectra database , inorganic chemistry , stereochemistry , organic chemistry , physics , catalysis , quantum mechanics , computer graphics (images) , computer science
Planar, sterically undemanding Ni, Pd, and Pt complexes of type (1) —useful donor components for CT complexes—have been synthesized from tetraethoxypropane, ethanol, HCl, H 2 S, and MCl 2 . The NMR spectra of Pt(ptt) 2 , (1) , M = Pt, X = S, suggest strong electron delocalization.