Transition‐Metal Complexes of Malonaldehyde and Dithiomalonaldehyde | Zendy

MuellerWesterhoff Ulrich T. | Zendy; Alscher Arnold | Zendy

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Transition‐Metal Complexes of Malonaldehyde and Dithiomalonaldehyde

Author(s) -

MuellerWesterhoff Ulrich T.,

Alscher Arnold

Publication year - 1980

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198006381

Subject(s) - steric effects , electron delocalization , delocalized electron , transition metal , chemistry , crystallography , planar , spectral line , metal , nmr spectra database , inorganic chemistry , stereochemistry , organic chemistry , physics , catalysis , quantum mechanics , computer graphics (images) , computer science

Planar, sterically undemanding Ni, Pd, and Pt complexes of type (1) —useful donor components for CT complexes—have been synthesized from tetraethoxypropane, ethanol, HCl, H 2 S, and MCl 2 . The NMR spectra of Pt(ptt) 2 , (1) , M = Pt, X = S, suggest strong electron delocalization.

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