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Template Polymerization of Rhodium( I ) with Rigid Bent Diisocyanide Ligands
Author(s) -
Efraty Avi,
Feinstein Irene,
Wackerle Lorenz,
Frolow Felix
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198006331
Subject(s) - rhodium , denticity , polymerization , bent molecular geometry , polymer , crystallite , chemistry , chelation , polymer chemistry , crystallography , bridging (networking) , materials science , stereochemistry , catalysis , organic chemistry , crystal structure , computer network , computer science
Two‐dimensional polymeric networks of the type [Rh(Bridge) 2 +Cl − ] n are present in the green polycrystalline material obtained from [Rh(CO) 2 Cl] 2 and bridging ligands such as 1,3‐diisocyanobenzene and 4,4′‐diisocyanodiphenylmethane. These bidentate ligands cannot form chelates. Information about the structure of the polymers was derived from X‐ray powder diagrams.