Premium
P 4 (N‐ i ‐C 3 H 7 ) 6 , a P 4 X 6 Molecule with and without Adamantane Structure
Author(s) -
Scherer Otto J.,
Andres Kurt,
Krüger Carl,
Tsay YiHung,
Wolmerhäser Gotthelf
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198005711
Subject(s) - molecule , crystallography , cryptand , adamantane , thermal decomposition , ring (chemistry) , chemistry , stereochemistry , ion , organic chemistry
The first P 4 X 6 molecule to have a cryptand structure , the title compound (1) , is formed on thermolysis of a (PNR) 2 ring bearing Me 3 SiNR and Cl as substituents. On prolonged heating, (1) assumes the adamantane structure, like all other P 4 X 6 molecules.