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Cyclic Carbodiimides in Nitrene Rearrangements
Author(s) -
Wentrup Curt,
Thétaz Célestin,
Tagliaferri Enrico,
Lindner Hans Jörg,
Kitschke Brigitte,
Winter HansWilhelm,
Reisenauer Hans Peter
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198005661
Subject(s) - nitrene , carbodiimide , chemistry , gas phase , spectroscopy , phase (matter) , polymer chemistry , organic chemistry , physics , quantum mechanics , catalysis
Convicing evidence for the first seven‐membered cyclic carbodiimide (2) was obtained on rearrangement of the nitrenes (1) and (3) in the gas phase, in solution, and in an argon matrix. At 10 K (2) is stable and can be detected by IR spectroscopy.