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A New Variant of the Amphoterism of Tin( II ) Hydroxide: Sn(OH) 2 as Stannio Complex Ligand
Author(s) -
du Mont WolfWalther,
Neudert Brigitte
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198005531
Subject(s) - tin , ligand (biochemistry) , hydroxide , metal , transition metal , chemistry , polymer , inorganic chemistry , crystallography , polymer chemistry , organic chemistry , catalysis , biochemistry , receptor
A novel mode of fixing a transition metal to an amphoteric inorganic polymer has been accomplished in the complexes (2) . Complexes having coordinative SnM bonds were formerly unknown. Sn(OH) 2 is still highly associated in (2) (M = Cr, W; R = Ph, Me).