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Electrochemical Oxidation of Dicarbene Complexes of the Type (Carbene) 2 MoL(CO) 3 : Interconversion Among Three Isomers via Electrochemical Redox Processes
Author(s) -
Rieke Reuben D.,
Kojima Hiroyuki,
Öfele Karl
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198005381
Subject(s) - electrochemistry , redox , carbene , chemistry , isocyanide , stereochemistry , photochemistry , inorganic chemistry , electrode , organic chemistry , catalysis
Unusual isomerizations have been observed in the new dicarbenemetal complexs (1): the three isomers undergo mutual interconversion via electrochemical redox processes (L = cyclohexyl isocyanide, PEt 3 , PPh 3 ).