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B 8 S 16 —An “Inorganic Porphine”
Author(s) -
Krebs Bernt,
Hürter HansUlrich
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198004811
Subject(s) - planar , hydrolysis , fusion , materials science , crystallography , chemistry , analytical chemistry (journal) , organic chemistry , computer science , computer graphics (images) , linguistics , philosophy
The extremely hydrolysis‐sensitive compound (BS 2 ) 8 , obtained by fusion of a mixture of B 2 S 3 and S 8 in vacuo (300/100°C), has been found by X‐ray structure analysis to be a planar porphine analogue. A second synthetic route starts from pre‐formed five‐membered rings.