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Intercalation Complexes of Metallocenes in Iron Oxide Chloride
Author(s) -
SchäferStahl Hartwig,
Abele Raimund
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198004771
Subject(s) - intercalation (chemistry) , ferrocene , crystal structure , mössbauer spectroscopy , chloride , chemistry , molecule , crystallography , electron , inorganic chemistry , oxide , metallocene , materials science , electrochemistry , organic chemistry , physics , electrode , polymer , quantum mechanics , polymerization
Assumption of “free” electrons in the intercalation complex (1) of FeOCl and ferrocene rationalizes the finding that the high‐spin Fe 3+ state of the FeOCl host lattice is retained on intercalation of the guest molecule (Mössbauer spectrum), while the Mössbauer absorptions of ferrocene disappear completely. The conductivity of the crystal also supports formulation as (1) .