(1,2,5,6‐η‐1,5‐Cyclooctadiene)‐ (1,2,7,‐η‐7‐methylbenzyl)(7,8‐η‐styrene)rhodium( I )—Antarafacial Fluctuation of the Benzyl Ligand and Temperature‐Dependent Coordination of Styrene | Zendy

Stühler HansOtto | Zendy

Premium

(1,2,5,6‐η‐1,5‐Cyclooctadiene)‐ (1,2,7,‐η‐7‐methylbenzyl)(7,8‐η‐styrene)rhodium( I )—Antarafacial Fluctuation of the Benzyl Ligand and Temperature‐Dependent Coordination of Styrene

Author(s) -

Stühler HansOtto

Publication year - 1980

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198004681

Subject(s) - rhodium , styrene , ligand (biochemistry) , chemistry , cyclooctadiene , nuclear magnetic resonance spectroscopy , 1,5 cyclooctadiene , medicinal chemistry , polymer chemistry , stereochemistry , copolymer , organic chemistry , catalysis , biochemistry , receptor , polymer

A fluxional η 3 ‐benzyl ligand , as is found in the new rhodium( I ) complex (1) , is stell a rarity. Its antarafacial fluctuation, detected by NMR spectroscopy above −40°C, is the first of its kind; it can only proceed via a form with Ph—C benzyl σ‐bond. Only the “σ form” exists at −100°C.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research