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Oxidation Reactions of Benzvalene: Ozonolysis, cis ‐Hydroxylation, Epoxidation, and Singlet Oxygen Addition
Author(s) -
Leininger Hartmut,
Christl Manfred
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198004581
Subject(s) - oxidizing agent , ozonolysis , hydroxylation , singlet oxygen , chemistry , bicyclic molecule , ring (chemistry) , oxygen , medicinal chemistry , photochemistry , organic chemistry , enzyme
Progress in the synthesis of endo,endo ‐disubstituted bicyclo[1.1.0]butanes such as (2) was achieved on reaction of benzvalene (1) with classical oxidizing agents. (1) is also suitable as a starting material for synthesizing other small‐ring polycycles with bicyclobutane partial structures.