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Triple‐Decker Sandwich Complexes of 4d and 5d Metals with cyclo ‐Triphosphorus as μ,η 3 ‐Ligand: Structural and Magnetic Properties
Author(s) -
Bianchini Claudio,
Di Vaira Massimo,
Meli Andrea,
Sacconi Luigi
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198004051
Subject(s) - triphos , ligand (biochemistry) , cationic polymerization , crystallography , chemistry , main group element , metal , stereochemistry , transition metal , materials science , polymer chemistry , organic chemistry , biochemistry , receptor , catalysis
Cationic triple‐decker complexes triphos‐M 1 ‐ cyclo ‐P 3 ‐M 2 ‐triphos , in which M 1 and 4d‐ and 5d‐metals, differ in their magnetic properties from the known complexes of 3d metals (in some cases considerably). Deviation in the complex with M 1 = Rh, M 2 = Ni is attributed to the fact that the P 3 group is not “centered”.