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Synthesis of Organotrimetal Polymers Using Trimetal Vapor‐Fluid Matrix Techniques
Author(s) -
Francis Colin G.,
Huber Helmut X.,
Ozin Geoffrey A.
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198004021
Subject(s) - polymer , front cover , matrix (chemical analysis) , linkage (software) , materials science , molecule , spectroscopy , polymer science , metal , chemical engineering , front (military) , polymer chemistry , cover (algebra) , chemistry , organic chemistry , composite material , physics , metallurgy , engineering , mechanical engineering , biochemistry , quantum mechanics , meteorology , gene
The linkage of three kinds of metal atoms (Cr, V, Ti) in the same liquid polymer and the generation of the CrV species have now been accomplished in poly(methylphenylsiloxane) at ca. −20°C (detection by UV/VIS spectroscopy). The nature of the bond is shown here and on the front cover of this journal.