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A Cubane‐Type Sn 4 N 3 O Cage
Author(s) -
Veith Michael,
Lange Holger
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198004011
Subject(s) - cage , cubane , adduct , chemistry , derivative (finance) , type (biology) , hydrolysis , stereochemistry , character (mathematics) , crystallography , combinatorics , geology , mathematics , organic chemistry , crystal structure , geometry , paleontology , financial economics , economics
The heterocubane derivative (2) , R = t Bu, generated by partial hydrolysis of the “open cage” (1) is one of the few examples of cubanes having a skeleton made up of three elements. Structural proof is provided, inter alia , by the “isosteric character” of the AlMe 3 adduct with the (SN‐ t Bu) 4 cage.