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Unusually Bridged Tungsten Complexes with W(ER) 2 W(ER) 3 W Skeleton (ES or Se; R C 2 H 5 , n ‐C 4 H 9 , or C 6 H 5 )
Author(s) -
KrauthSiegel Luise R.,
Schulze Wolfgang,
Ziegler Manfred L.
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198003971
Subject(s) - tungsten , crystallography , chemistry , skeleton (computer programming) , stereochemistry , organic chemistry , programming language , computer science
Novel “non‐cyclic trinuclear clusters” (1) — (3) arise alongside other products on reaction of the thiolates Pb(SR) 2 or the selenol HSeC 6 H 5 with η 7 ‐C 7 H 7 W(CO) 2 I. The unusual molecular structure has been confirmed in (2) by X‐ray methods.