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2‐ tert ‐Butyl‐2 H ‐isoindole: A Partner for Reactions with Electrophiles
Author(s) -
Kreher Richard,
Use Götz
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198003201
Subject(s) - isoindole , electrophile , chemistry , protonation , medicinal chemistry , alkylation , bicyclic molecule , organic chemistry , catalysis , ion
A rare case among the bicyclic 10π‐heteroarenes having o ‐quinonoid structure is that of 2‐ tert ‐butyl‐2 H ‐isoindole (1) , for it can be protonated, alkylated, and subjected to electrophilic coupling with arenediazonium salts to give azo compounds.