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Exceedingly Mild Desulfurization of Thiols by Sodium Triethylhydroborate and Transition Metal Chlorides
Author(s) -
Alper Howard,
Prince Trish L.
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198003151
Subject(s) - flue gas desulfurization , transition metal , chemistry , sodium , inorganic chemistry , sulfur , organic chemistry , catalysis
Hydrocarbons can be obtained from thiols at room temperature/−78 °C with the new reduction system given below. The procedure is suitable for aromatic, benzylic, and aliphatic thiols; CoCl 2 can be used instead of FeCl 2 . Other chlorides are less effective.