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X‐Ray Structure Analysis of Bis( O,O ′‐diphenyldithiophosphato)tin( II ), a Bicyclic Dimer Held Together by η 6 ‐C 6 H 5 /Sn II Interactions
Author(s) -
Lefferts J. L.,
Hossain M. B.,
Molloy K. C.,
van der Helm D.,
Zuckerman J. J.
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198003091
Subject(s) - tin , dimer , bicyclic molecule , chelation , crystallography , chemistry , stereochemistry , materials science , inorganic chemistry , organic chemistry
A dimeric tin complex of highly unusual structure has been obtained as part of a program to synthesize biocidal tin compounds [eq. (1)]. Two ligands are normal chelating agents, and two form bridges; two η 6 ‐C 6 H 5 ‐Sn II interactions stabilize the dimer.