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1,5‐Dihydropentalene by Tandem Carbene‐Carbene Rearrangement
Author(s) -
Brinker Udo H.,
Fleischhauer Ilona
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - Uncategorized
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198003041
Subject(s) - carbene , tandem , chemistry , materials science , organic chemistry , composite material , catalysis
A new type of carbene‐carbene rearrangement transforms (1) in a single synthetic step into 1,5‐dihydropentalene. 12 C‐labeling suggests the reaction course shown below.