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First Fixation of the Unstable Species Sulfur Monoxide in a Cluster: Synthesis and Structure of Fe 3 (CO) 9 (S)SO
Author(s) -
Markó László,
MarkóMonostory Bernadett,
Madach Thomas,
Vahrenkamp Heinrich
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198002261
Subject(s) - cluster (spacecraft) , sulfur , chemistry , monoxide , chemisorption , sulfite , carbon monoxide , sulfide , inorganic chemistry , ligand (biochemistry) , crystallography , sulfite reductase , adsorption , catalysis , organic chemistry , biochemistry , enzyme , receptor , computer science , reductase , programming language
The first compound to contain the SO ligand , the cluster (1) , can be regarded as an intermediate of reduction of sulfite to sulfide by iron carbonyl hydrides. The Fe 3 SO grouping is of interest as a model for chemisorption of SO 2 onto metals.