First Fixation of the Unstable Species Sulfur Monoxide in a Cluster: Synthesis and Structure of Fe 3 (CO) 9 (S)SO | Zendy

Markó László | Zendy; MarkóMonostory Bernadett | Zendy; Madach Thomas | Zendy; Vahrenkamp Heinrich | Zendy

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First Fixation of the Unstable Species Sulfur Monoxide in a Cluster: Synthesis and Structure of Fe 3 (CO) 9 (S)SO

Author(s) -

Markó László,

MarkóMonostory Bernadett,

Madach Thomas,

Vahrenkamp Heinrich

Publication year - 1980

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198002261

Subject(s) - cluster (spacecraft) , sulfur , chemistry , monoxide , chemisorption , sulfite , carbon monoxide , sulfide , inorganic chemistry , ligand (biochemistry) , crystallography , sulfite reductase , adsorption , catalysis , organic chemistry , biochemistry , enzyme , receptor , computer science , reductase , programming language

The first compound to contain the SO ligand , the cluster (1) , can be regarded as an intermediate of reduction of sulfite to sulfide by iron carbonyl hydrides. The Fe 3 SO grouping is of interest as a model for chemisorption of SO 2 onto metals.

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