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“α,α,α”‐, “α,β,α”‐ and “α,α,β”‐Trioxatris‐σ‐homotropone
Author(s) -
Seppelt Wolfgang,
Fritz Hans,
Rücker Christoph,
Prinzbach Horst
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198002141
Subject(s) - tris , ion , chemistry , computational chemistry , stereochemistry , combinatorial chemistry , organic chemistry , biochemistry
The three stereoisomeric triepoxycycloheptanones (1) , which could be transformed, inter alia , into trioxonines and into potentially “tris‐homobenzenoid” carbenium ions, have been synthesized separately: the two “symmetrical” isomers from readily accessible (2) , and the unsymmetrical isomer from (3) .