Double Addition of a Nucleophile to Carbyne and Carbonyl C‐Atom:  S ‐Phenyl 2‐Phenyl‐2‐(phenylthio)thioacetate from  trans ‐Bromotetracarbonyl(phenylcarbyne)chromium and Thiophenolate | Zendy

Fischer Ernst Otto | Zendy; Röll Werner | Zendy

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Double Addition of a Nucleophile to Carbyne and Carbonyl C‐Atom: S ‐Phenyl 2‐Phenyl‐2‐(phenylthio)thioacetate from trans ‐Bromotetracarbonyl(phenylcarbyne)chromium and Thiophenolate

Author(s) -

Fischer Ernst Otto,

Röll Werner

Publication year - 1980

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198002051

Subject(s) - carbyne , nucleophile , chromium , yield (engineering) , chemistry , carbon atom , medicinal chemistry , atom (system on chip) , stereochemistry , carbene , ring (chemistry) , materials science , organic chemistry , catalysis , computer science , metallurgy , embedded system

Reaction of thiophenolate with the carbyne complex (1) resembles neither that of phenolate nor that of selenophenolate [which yield PhCH 2 —COOPh and (CO) 5 Cr(PhSeSePh) and (CO) 4 Cr(μ‐SePh) 2 Cr(CO) 4 , respectively]. Instead, unexpected double addition gives the thiol ester (2) .

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