Heterogeneously Catalyzed Gas‐Phase Bromination of Trifluoromethane | Zendy

Bock Hans | Zendy; Mintzer Jan | Zendy; Wittmann Jörg | Zendy; Russow Jürgen | Zendy

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Heterogeneously Catalyzed Gas‐Phase Bromination of Trifluoromethane

Author(s) -

Bock Hans,

Mintzer Jan,

Wittmann Jörg,

Russow Jürgen

Publication year - 1980

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198001471

Subject(s) - activated charcoal , catalysis , gas phase , charcoal , phase (matter) , halogenation , chemical engineering , materials science , chemistry , analytical chemistry (journal) , chromatography , organic chemistry , adsorption , engineering

The optimization of a heterogeneously catalyzed gas‐phase reaction by PE spectroscopy is demonstrated for the production of F 3 CBr, an extinguishing agent used in automatic fire extinguishing installations. A specially developed (PE spectroscopic) gas‐analysis technique permits screening of catalysts (and conditions). The best results were obtained with FeCl 3 /KBr/activated charcoal.

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